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Communities in RUIdeRA
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Recent Submissions
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Artistas y máquinas: diálogos en el desarrollo del arte digital
(Consorci de Museus de la Comunitat Valenciana, 2022) Alcalá Mellado, José Ramón; Casares, Nilo
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The Development of Digital Narratives. Case study: Fred Adam and the pioneering multimedia interactive creations in the MIDE of Cuenca during the 1990s
(Donau-Universität, 2019) Alcalá Mellado, José Ramón; Escribano Belmar, Beatriz
In the 1990s, the International Museum of Electrography of Cuenca (MIDE), thanks to a newly-created artist-in-residency program, welcomed artists from all over the world who experimented with new media during this historical era of pioneering Media Art. One of the first artists to visit the MIDE was Fred Adam, a French artist, still a student at the École des Beaux-Arts in Nantes, who carried out countless researches in this creative field during his stay. One example that had a greater repercussion was the creation of digital narratives in interactive multimedia.
This work seeks to put some of the pioneering media artworks into value, building their story, and working to recover and preserve them and update their languages so that they become accessible again. Only through this institutional and personal commitment to history can we recover, divulge and give access to the immense artistic heritage that generated and continues to generate the art that uses or has as a reference on new media.
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DFT-Studies on Cobalt Catalyzed Cyclotrimerization Reactions. Mechanism and Origin of Reaction Improvement under Microwave Irradiation
(Wiley-VCH, 2012) Rodríguez García, Antonio Manuel; Cebrián, Cristina; Prieto, Pilar; García, José Ignacio; Hoz Ayuso, Antonio de la; Díaz Ortiz, Ángel
A DFT computational mechanistic study of the [2+2+2] cyclotrimerization of a diyne with benzonitrile, catalyzed by a cobalt complex, has been carried out. Three alternative catalytic cycles have been examined together with the precatalytic step (responsible for the induction period). The favored mechanism takes place by means of an intramolecular metal-assisted [4+2] cycloaddition. The beneficial role of microwave activation has been studied. It is concluded that microwave irradiation can decrease the catalytic induction period through thermal effects and can also increase the triplet lifetime and promote the reaction, thus improving the final yield.
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Continuous-flow microliter microwave irradiation in the synthesis of isoxazole derivatives. An optimization procedure
(Thieme, 2012) Hoz Ayuso, Antonio de la; Rodríguez García, Antonio Manuel; Juan, Alberto; Gómez, M. Victoria; Moreno Moreno, Andrés
An efficient method was developed for the synthesis of 3,4,5-trisubstituted and 3,5-disubstituted isoxazoles by using continuous-flow microwave-heated microreactors. A study on the separate effects of the temperature, continuous-flow regime, and microwave irradiation showed that the continuous-flow regime had important effects for less reactive diketones, where microwave heating enhanced the reaction, permitting the formation of 5-methyl-3-phenylisoxazole, which was not formed in the absence of microwaves.