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dc.contributor.authorAbdiaj, Irini
dc.contributor.authorHuck, Lena
dc.contributor.authorMateo, José Miguel
dc.contributor.authorde la Hoz, Antonio
dc.contributor.authorGomez, M. Victoria
dc.contributor.authorDíaz-Ortiz, Angel
dc.contributor.authorAlcázar, Jesús
dc.date.accessioned2018-09-18T12:46:13Z
dc.date.available2018-09-18T12:46:13Z
dc.date.issued2018-09-24
dc.identifier.citationAngew. Chem. Int. Ed.es_ES
dc.identifier.issn1433-7851
dc.identifier.urihttp://hdl.handle.net/10578/18335
dc.description.abstractA visible light-induced Negishi cross-coupling, through activation of a Pd(0)-zinc complex, is reported. This new photocatalytic process allows the expansion of the scope of zinc enolates in the Negishi coupling reaction with deactivated aryl halides. NMR experiments in the presence and absence of light confirmed that the formation of the palladium-zinc complex is key for accelerating the oxidative addition step.es_ES
dc.formatapplication/pdfes_ES
dc.language.isoenes_ES
dc.publisherWILEY-VCHes_ES
dc.rightsinfo:eu-repo/semantics/openAccesses_ES
dc.subjectPhotocatalysises_ES
dc.subjectVisible lightes_ES
dc.subjectPd Negishi couplinges_ES
dc.subjectC(sp3)–C(sp2) couplinges_ES
dc.subjectFlow Chemistryes_ES
dc.titlePhotoinduced Palladium Negishi Cross-Coupling Through Visible Light Absorption of Palladium-Zinc Complexeses_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.identifier.DOIDOI: 10.1002/anie.201808654
dc.relation.projectIDMarie Sklodowska-Curie (grant agreement No 641861)es_ES
dc.relation.projectIDMINECO (CTQ2017-84825-R)es_ES
dc.relation.projectIDRamón y Cajal program (RYC2007-14768)es_ES


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